Kugwiritsa Ntchito Mafuta Opaka Amine Polyglycerol Ether Surfactants

Kapangidwe ka ether ya fatty amine polyglycerolzinthu zopangira ma surfactantsakuwonetsedwa pachithunzi chili pansipa. Magulu awo okonda madzi amapangidwanso ndi magulu a hydroxyl ndi ma bond a ether. Komabe, makonzedwe osinthasintha a magulu a hydroxyl ndi ma bond a ether amasiyana ndi ma surfactants a polyoxyethylene ether nonionic, omwe amalamulidwa ndi ma bond a ether. Akasungunuka m'madzi, kupatula kupanga ma bond ofooka a hydrogen pakati pa ma atomu a okosijeni a ma bond a ether ndi ma atomu a hydrogen m'madzi monga ma surfactants a polyoxyethylene ether, amathanso kuyanjana ndi madzi kudzera m'magulu a hydroxyl. Pachifukwa ichi, ma surfactants a fatty amine polyglycerol ether amatha kusungunuka bwino m'madzi ndi ma glycidol adducts ochepa, ndipo hydrophilicity yawo ndi yapamwamba kwambiri kuposa ya ma surfactants a polyoxyethylene ether.

Kuphatikiza apo, ma fatty amine polyglycerol ether surfactants ali ndi kapangidwe ka ma organic amines, zomwe zimawapatsa mphamvu za ma nonionic surfactants komanso ma cationic surfactants. Pamene chiwerengero cha ma adducts chili chochepa, amasonyeza makhalidwe a ma cationic surfactants, monga kukana asidi koma kusalolera kwa alkali ndi ntchito zina zopha mabakiteriya. Pamene chiwerengero cha ma adducts chikuwonjezeka, mphamvu zawo za nonionic zimakhala zoonekera kwambiri. Sizidzagwa m'ma alkaline solutions ndipo ntchito yawo pamwamba imakhalabe yofanana. Ndi kuwonjezeka kwa nonionicity ndi kufooka kwa cationicity, kusagwirizana kwawo ndi ma anionic surfactants kumachepa, zomwe zimapangitsa kuti mitundu iwiri ya ma surfactants igwiritsidwe ntchito pamodzi.

Yogwiritsidwa ntchito mumakampani ochapira zovala

Ma surfactants a Fatty Amine Polyglycerol Ether ali ndi makhalidwe osiyanasiyana kutengera kuchuluka kwa ma adduct awo. Kuchuluka kwa adduct kochepa kumawapatsa makhalidwe a ma surfactants a cationic, kukulitsa kusungunuka kwawo kutentha kochepa komanso kupereka detergent yabwino kwambiri pa kutentha kwakukulu. Kuchuluka kwa adduct kukakwera, khalidwe lawo losakhala ionic limawonekera kwambiri. Sizidzagwa mu alkaline solutions ndipo ntchito yawo pamwamba imakhalabe yofanana. Ndi makhalidwe abwino a nonionic komanso makhalidwe ofooka a cationic, kuwasakaniza ndi ma surfactants a anionic kungachepetse kwambiri kupsinjika kwa pamwamba ndikuwonjezera mphamvu ya emulsifying ndi wetting. Mofanana ndi hydrophilicity ndi steric effect ya polyoxyethylene unyolo, ma surfactants awa amathanso kuletsa kwambiri mvula kapena kusonkhana kwa sopo. Kuphatikiza apo, ma ether a fatty amine polyglycerol ali ndi mphamvu zofewa komanso zotsutsana ndi static, zomwe zimatha kuthetsa vuto la kusamva bwino kwa zinthu za ulusi pambuyo posamba.

Yogwiritsidwa ntchito pamankhwala ophera tizilombo

Kupatula pa mphamvu yabwino kwambiri yopangira ma surfactants osakhala ma ionic, ma surfactants a fatty amine polyglycerol ether alinso ndi mphamvu zina zophera mabakiteriya komanso zophera majeremusi za ma surfactants a cationic, zomwe zimapangitsa kuti akhale ma surfactants ophatikizana ambiri. Amatha kuwonjezera kukhuthala ndikuwongolera kusungunuka kutentha kochepa, zomwe zimapangitsa kuti kutentha kwa ma microemulsions ophera tizilombo omwe amapangidwa nawo kusinthasintha. Mtundu uwu wa composite surfactant, fatty amine polyglycerol ether, umakhala ndi mphamvu zambiri popanga ma microemulsions a O/W. Umathandiza kuchepetsa mlingo wa ma surfactants ndikuchepetsa ndalama zopangira.

Konzani mankhwala oletsa kusinthasintha kwa kutentha

Ma surfactants amafuta a polyglycerol ether amatha kupanga filimu yamadzi yopitilira pamwamba pa ulusi kudzera mu ma bond a haidrojeni pakati pa magulu awo okonda madzi, magulu a hydroxyl ndi mamolekyu amadzi, motero amapereka kuyamwa kwabwino kwa chinyezi ndi conductivity. Pakadali pano, amatha kupanga filimu yamafuta okonda madzi pamwamba pa ulusi kuti achepetse kukangana kwa ulusi ndi kupanga magetsi osasunthika, komanso kupatsa ulusi kufewa komanso kusalala. Kuphatikiza apo, gawo la hydrophobic la ma surfactants amafuta a polyglycerol ether limafanana ndi la ma surfactants amafuta a polyglycerol ether. Popeza glycidol m'malo mwa ethylene oxide imawonjezeredwa ku gawo lake lokonda madzi, imakhala ndi hydrophilicity yamphamvu. Chifukwa chake, kuyamwa kwake kwa chinyezi ndi magwiridwe antchito ake kumaposa ma surfactants wamba a polyoxyethylene ether. Kuphatikiza apo, ma surfactants amafuta a polyglycerol ether ndi ochepa poizoni komanso okwiyitsa kuposa ma surfactants a cationic, zomwe zimapangitsa kuti akhale othandizira oteteza kutentha kwambiri.

Konzani pang'onozinthu zosamalira thupi

Pokonzekera ma surfactants a fatty amine polyglycerol ether ochokera ku glycidol, kapangidwe ka ma ethers a fatty amine polyglycerol kamakhala ndi ma bond a ether osinthika ndi magulu a hydroxyl m'malo molamulidwa ndi ma bond a ether. Izi zimaletsa kupangika kwa dioxane, zomwe zimapangitsa kuti ma surfactants awa akhale otetezeka kuposa ma surfactants a polyoxyethylene ether. Kuphatikiza apo, ma surfactants a fatty amine polyglycerol ether ali ndi magulu ambiri a hydroxyl, omwe amawonjezera hydrophilicity, amachepetsa kukwiya komanso amapereka zotsatira zochepa pa thupi la munthu. Chifukwa chake, amagwiritsidwa ntchito popanga zinthu zosamalira thupi, makamaka za makanda ndi ana aang'ono.

Kugwiritsa ntchito pochiza utoto pamwamba

Kafukufuku wasonyeza kuti ma surfactants osakhala a ionic a mtundu wa amine amafuta amapereka zotsatira zabwino kwambiri pakusintha pamwamba pa utoto wobiriwira wa phthalocyanine. Kuchita bwino kumeneku kumachitika chifukwa cha zifukwa zotsatirazi: ma surfactants otere amatha kumizidwa pamwamba pa utoto mwa kupanga ma hydrogen bond pakati pa ma atomu a hydrogen m'magulu a hydroxyl (-OH) ndi amino groups (-NH) ndi ma atomu a nayitrogeni pamwamba pa utoto wobiriwira wa phthalocyanine. Ma lipophilic hydrocarbon chains awo amapanga filimu yophimba yomwe imamizidwa. Chophimba ichi chimalepheretsa bwino kusonkhana kwa tinthu ta pigment panthawi yowuma ndikuletsa kukula kwa tirigu wa kristalo, pamapeto pake kutulutsa tinthu ta pigment ndi makristasi abwino.

Pamene utoto wosinthidwawo waikidwa mu organic media, unyolo wa hydrocarbon, womwe umagwirizana bwino ndi organic media, umasungunuka mwachangu kuti upange filimu yosungunuka. Izi zimathandiza kufalikira kwa tinthu ta pigment ndikuletsa kuyandama kwa tinthu timeneti tikakhala pafupi. Izi zimawonjezeka pamene unyolo wa hydrocarbon umatalika ndipo filimu yosungunukayo imakhuthala, zomwe zimathandiza kukonza tinthu ta pigment ndikukwaniritsa kufalikira kwa tinthu tating'onoting'ono. Magulu a hydrophilic a ma surfactants amapanga filimu yosungunuka pambuyo pa madzi, zomwe zimalepheretsanso kuyandama pakati pa tinthu ta pigment ndikuwonjezera kufalikira kwawo.

Mafuta a polyglycerol ether surfactants ali ndi mphamvu yowonjezereka ya hydrophilicity ndipo amatha kupanga mafilimu okhuthala okhala ndi madzi ambiri. Chifukwa chake, utoto wothiridwa ndi ma surfactants awa umafalikira mosavuta m'madzi okhala ndi tinthu tating'onoting'ono, zomwe zikusonyeza kuti angagwiritsidwe ntchito bwino pochiza utoto wobiriwira wa phthalocyanine pamwamba.