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Amphoteric Surfactant HJ40: Balancing Mildness and Performance in Hard Water, High-Alkali and High-Salt Systems — Released by Qixuan Chemical

For decades of surfactant R&D and application, formulators are frequently confronted with a long-standing dilemma: must cleaning power and mildness always be mutually exclusive?
In personal care formulations, this trade-off directly translates to end-user sensory experience. In industrial formulations, however, it determines production cost, rework rate and customer complaints. For cleaning agents intended to function under high-alkali and high-electrolyte loading, formulators tend to rely heavily on anionic surfactants. In oilfield applications, formation water may carry tens of thousands of mg/L total dissolved solids, causing conventional surfactants to precipitate instantly. For pesticide aerial application and asphalt emulsification, compatibility with cationic components becomes a prerequisite, while most common anionic surfactants will precipitate immediately once mixed with cationic species.
Against such challenging formulation scenarios, Shanghai Qixuan Chemical Technology Co., Ltd. officially launches HJ40 (Sodium capryliminodipropionate, CAS No. 94441-92-6, 40% active content).

1

Molecular Profile: C8 Alkyl Chain with Dual Propionate Carboxylate Groups

HJ40 features a straightforward molecular architecture: a linear n-octyl (C8) alkyl group attached to a tertiary amine nitrogen, which is further substituted with two propionate side chains neutralized as sodium carboxylate salts. This unique structure delivers three core advantages.

True Amphoteric Characteristics Its carboxylate groups undergo pH-dependent dissociation: under acidic conditions, the amine moiety becomes protonated, rendering the molecule predominantly cationic; from neutral to alkaline environments, the two carboxylate groups dissociate to confer anionic behaviour. HJ40 maintains stability across a broad pH window.
Short C8 Alkyl Chain Merit Short-chain analogues deliver superior solubility and diffusion kinetics when rapid wetting, low residue and electrolyte tolerance are required. HJ40 does not require substantial solubilizers such as ethanol or urea and remains fully soluble in hard water matrices.
Dual Carboxylate Groups Provides multiple binding sites, endowing the product with enhanced chelating capacity, calcium/magnesium tolerance and solid-surface anchoring performance compared with mono-carboxylate betaines.

2

Core Performance Highlights

  • ✔ 1. Excellent Tolerance to Hard Water and Electrolytes: HJ40 resists precipitation and soap scum formation in water hardness above 20 °H. Permits high loading of sodium carbonate, sodium metasilicate, EDTA-4Na without phase separation.
  • ✔ 2. Compatibility with Cationic Systems: Most distinctive edge. Can be co-formulated with quaternary ammonium biocides, cationic softeners, and amine-based emulsifiers without insoluble complex formation.
  • ✔ 3. Mildness Comparable to Amino-Acid Surfactants and APGs: Demonstrates markedly lower defatting potential than AES or LAS. Critical for operator skin safety in manual cleaning.
  • ✔ 4. Broad pH Stability Window: Chemically stable from acidic descaling environments up to highly alkaline degreasing baths above pH 12.
  • ✔ 5. Favourable Biodegradability and Low Aquatic Toxicity: Linear C8 aliphatic structure with no branched chains or alkylphenol ethoxylates, ensuring predictable environmental fate.

3

Industry-Specific Applications

Cleaning Industry

As a high-alkali co-surfactant, HJ40 stabilizes emulsions and improves rinsing performance. For CIP systems, its moderate foam profile reduces antifoam dosage. In acidic metal cleaning, it ensures compatibility with corrosion inhibitors.

Oilfield Chemistry

Exhibits robust calcium/magnesium tolerance. Suitable for surfactant flooding, fracturing flowback aids, and paraffin removal. Recommended loading range: 3%–10% as a compatibility modifier.

Agrochemicals (Agro-emulsifiers)

Provides outstanding stability in hard water and compatibility with metallic nutrient fertilisers. Serves as a wetting penetrant for water-based agrochemical formulations and aerial spray programmes.

Asphalt and Emulsified Asphalt

Acts as a stabilising co-additive in cationic systems. Improves shelf-life, retards premature demulsification, and enhances adhesion onto aggregate surfaces.

Mineral Flotation

Functions as a foaming agent and auxiliary collector. Maintains system stability under high-salinity pulp conditions and minimises reagent loss.

Personal Care

Mild profile supports incorporation into baby shampoo, sensitive-skin facial cleansers, and amino-acid surfactant systems as a foam booster.

4

Formulation Guidelines

  • Recommended Dosage: 3%–10% (as supplied) as a primary surfactant; 1%–5% as a compatibility additive.
  • Feeding Protocol: Fully water-soluble; add directly to aqueous phase. Pre-dilute when mixing with concentrated alkali to avoid gel-phase formation.
  • Compatible Co-Components: Stable with LAS, AES, AEO series, APGs, and quaternary ammonium salts.
  • Notes: At pH < 2, the molecule shifts toward cationic character, affecting foaming behaviour.

5

Supply Information

HJ40 is supplied as a 40% aqueous solution (colourless to pale yellow transparent liquid). Packaging options include 25 kg / 50 kg plastic drums and 200 kg drums / 1000 kg IBC totes.

Our application laboratory can conduct compatibility testing tailored to your target system: alkaline degreasing, high-salinity oilfield fluid, water-based agrochemicals, emulsified asphalt or mineral flotation.

Amphoteric surfactants were once considered niche auxiliary additives. Today, rising requirements for mildness and electrolyte resistance have elevated them into structural components. HJ40 achieves a harmonious combination of mildness, salt tolerance, and broad formulation compatibility.

Shanghai Qixuan Chemical Technology Co., Ltd. Please contact our sales and technical application team for samples, COA and supporting technical documentation.

Post time: Nov-10-2026